Stretchable electronics have experienced remarkable progress, especially in sensors and wireless communication systems, attributed to their ability to conformably contact with rough or uneven surfaces. However, the development of complex, multifunctional, and high-precision stretchable electronics faces substantial challenges, including instability at rigid-soft interfaces and incompatibility with traditional high-precision patterning technologies. Metallized electrospun nanofibers emerge as a promising conductive filler, offering exceptional stretchability, electrical conductivity, transparency, and compatibility with existing patterning technologies. Here, this review focuses on the fundamental properties, preparation processes, patterning technologies, and application scenarios of conductive stretchable composites based on metallized nanofibers. Initially, it introduces the fabrication processes of metallized electrospun nanofibers and their advantages over alternative materials. It then highlights recent progress in patterning technologies, including collector collection, vapor deposition with masks, and lithography, emphasizing their role in enhancing precision and integration. Furthermore, the review shows the broad applicability and potential influence of metallized electrospun nanofibers in various fields through their use in sensors, wireless systems, semiconductor devices, and intelligent healthcare solutions. Ultimately, this review seeks to spark further innovation and address the prevailing challenges in stretchable electronics, paving the way for future breakthroughs in this dynamic field.

Recently, stretchable electronics combined with wireless technology have been crucial for realizing efficient human-machine interaction. Here, we demonstrate highly stretchable transparent wireless electronics composed of Ag nanofibers coils and functional electronic components for power transfer and information communication. Inspired by natural systems, various patterned Ag nanofibers electrodes with a net structure are fabricated via using lithography and wet etching. The device design is optimized by analyzing the quality factor and radio frequency properties of the coil, considering the effects of strain. Particularly, the wireless transmission efficiency of a five-turn coil drops by approximately only 50% at 10 MHz with the strain of 100%. Moreover, various complex functional wireless electronics are developed using near-field communication and frequency modulation technology for applications in content recognition and long-distance transmission (>1 m), respectively. In summary, the proposed device has considerable potential for applications in artificial electronic skins, human healthcare monitoring and soft robotics.