Elastomers are known for their strain-rate-dependent properties not only to quasistatic but also to high strain rate deformations, where mechanical behavior is significantly affected by inertia. Concurrently, environmental changes, such as temperature and humidity variations, can impact their stress response to deformation. This study investigates the effects of material layers within neoprene samples on mitigating these environmental changes. While the presence of an intermediate layer proves effective against temperature and humidity influence, it fails to block the impact of increasing high strain rates. Moreover, the different humidity levels at room and elevated temperatures do not significantly alter the mechanical behavior of filled neoprene samples compared to pure neoprene. Notably, in unfilled neoprene, an increase in humidity levels, other than an absolutely dry environment, leads to a notable stress level rise at room temperature, while under elevated temperature conditions, there is a significant stress decrease with increasing humidity. However, neoprene filled with polyester/cotton or nylon displays resilience to diminishing mechanical behavior under various temperature and humidity regulations, indicating that the material layer within these samples effectively "protects" the rubbers from potential stress lapses observed in unfilled neoprene. While a high strain rate compression affects the behavior of the filled variants significantly, increasing humidity and temperature have minimal impact on their stress levels. These findings offer valuable insights into the dynamic responses of elastomers to environmental changes, highlighting the advantages of using filled rubbers in diverse applications.

Polymers may absorb fluids from their surroundings via the natural phenomenon of swelling. Dimensional changes due to swelling can affect the function of polymer components, such as in the case of seals, microfluidic components and electromechanical sensors. An understanding of the swelling behavior of polymers and means for controlling it can improve the design of polymer components, for example, for the previously mentioned applications. Carbon-based fillers have risen in popularity to be used for the property enhancement of resulting polymer composites. The present investigation focuses on the effects of three carbon-based nano-fillers (graphene nano-platelets, carbon black, and graphene nano-scrolls) on the dimensional changes of polydimethylsiloxane composites due to swelling when immersed in certain organic solvents. For this study, a facile and expedient methodology comprised of optical measurements in conjunction with digital image analysis was developed as the primary experimental technique to quantify swelling dimensional changes of the prepared composites. Other experimental techniques assessed polymer cross-linking densities and elastic mechanical properties of the various materials. The study revealed that the addition of certain carbon-based nano-fillers increased the overall swelling of the composites. The extent of swelling further depended on the organic solvent in which the composites were immersed in. Experimental findings are contrasted with published models for swelling prediction, and the role of filler morphology on swelling behavior is discussed.