Multi-configuration Dirac-Hartree-Fock calculations of forbidden transitions within the 3d ground configurations of highly charged ions ( = 72-83)
Extensive self-consistent multi-configuration Dirac-Hartree-Fock (MCDHF) calculations are performed for the 3s3p3d ( = 1-9) ground configurations of highly charged ions ( = 72-83). Complete and consistent datasets of excitation energies, wavelengths, line strengths, oscillator strengths, and magnetic dipole (M1) and electric quadrupole (E2) transition rates among all these levels are given. We have compared our results with the results available in the literature and the accuracy of the data is assessed. We predict new energy levels and transition probabilities where no other experimental or theoretical results are available, which will form the basis for future experimental work.
Recommended electron-impact excitation and ionization cross sections for Be I
Analytic fits to the recommended electron-impact excitation and ionization cross sections for Be I are presented. The lowest 19 terms of configurations 2 ( ≤ 4) and 2 terms below the first ionization limit are considered. The fits are based on the accurate calculations with the convergent close coupling (CCC) method as well as the B-spline R-matrix (BSR) approach. The fitted cross sections provide rate coefficients that are believed to approximate the original data within 10% with very few exceptions. The oscillator strengths for the dipole-allowed transitions between all the considered states are calculated with the relativistic multi-configuration Dirac-Hartree-Fock (MCDHF) approach and compared with the CCC and BSR results. This comparison shows a very good agreement except for a handful of cases with likely strong cancellations.