"Blue energy" could be produced by exploiting the large salinity gradient between geothermal fluids and freshwater through a SaltPower system. This study is an attempt to select the most favorable chemicals to avoid injectivity issues when a diluted geothermal fluid resulting from the SaltPower system is returned to the reservoir. Three synthetic chelating agents (oxalic acid, EDTA, and EDDS) and one natural (humic acid) were evaluated through speciation simulations and isothermal titration calorimetry (ITC) experiments. The speciation simulation results indicate that the degree of complexing is highly dependent on pH and chelating agent type. The ITC experiments show that the total heat for the formation of soluble metal-ligand complexes in the rock + geothermal brine system follows: EDTA > EDDS > oxalic acid > humic acid. The simulations and calorimetry results suggest that EDTA could be used to avoid the precipitation of Fe(III) oxides and other minerals (e.g., calcite and dolomite) inside the porous media upon the reinjection of diluted geothermal brine coming from SaltPower electricity production.

A large share of the primary energy is consumed to provide space heating. Geothermal energy offers a regenerative alternative. For reasons of efficiency and environmental protection, it is important to ensure the system integrity of a borehole heat exchanger (BHE). Previous investigations have focused on the individual components of the BHE or on the grout and pipe systems' integrity. This study focused on the analysis of the hydraulic system integrity of the complete subsoil-grout-pipe system as well as possible thermally induced changes. For this purpose, a pilot-scale experiment was built to test a 1-m section of a typical BHE under in situ pressure, hydraulic and temperature conditions. During the tests the hydraulic system permeability of the soil and the BHE was measured continuously and separately from each other. In addition, the temperature monitoring array was installed in a 50-cm cross-sectional area. Significant temperature-related fluctuations in the sealing performance could be observed. Hydraulic conductivity limits required by VDI 4640-2 (Thermal use of the underground-ground source heat pump systems, 2019) were exceeded without frost action. The succeeding application of freeze-thaw cycles further enhances the system permeability. The study shows that the thermally induced effects on the system integrity of the BHE are larger and more significant than the subsequent frost-induced effects. The hydrophobic character of the high-density polyethylene (PE-HD) pipes as well as its high coefficient of thermal expansion seem to be the main points of weakness in the system. Optimization research should focus on the interface connection between grout and pipe, whereby hydrophilic pipe materials such as stainless steel or aluminum should also be considered as well as manipulation of the pipe surface properties of PE-HD.

Hydraulic stimulation of enhanced deep geothermal reservoirs commonly targets pre-existing joint networks with the goal of increasing reservoir permeability. Here, we study the permeability and strength of joint-free and jointed Buntsandstein sandstones from the EPS-1 exploratory borehole at the Soultz-sous-Forêts geothermal site (France). The studied jointed samples contain naturally formed fractures that are variably filled with secondary mineralisation. We find that the permeability of these rocks is more sensitive to the presence and orientation of bedding than to the presence of joints at the scale of the samples: permeability is lowest in samples where bedding is oriented perpendicular to the direction of fluid flow. While well-sealed joints can act as barriers to fluid flow, partially filled joints neither inhibit nor promote fluid flow with respect to their joint-free counterparts. These samples were then deformed under triaxial conditions to assess (1) whether deformation reactivates pre-existing joints, and (2) how permeability changes as a result of deformation. We find that the mechanical response of the rocks depends on the extent to which joints are sealed. Well-sealed joints locally increase rock strength and experimentally induced fractures do not exploit pre-existing joint surfaces; partially sealed joints, by contrast, act as planes of weakness that localise strain. Although the permeability of all samples increased during deformation, permeability increase was largest in samples with poorly filled joints. We conclude that hydraulic stimulation operations must carefully consider the extent to which targeted joint networks are filled. Partially sealed joints are ideal targets for stimulation: these features act as planes of weakness within the rock mass and their reactivation can result in significant increases in permeability. By contrast, well-sealed joints may increase rock strength locally and may never reactivate during stimulation, making them poor targets for permeability enhancement.