Water pollution continues to be one of the greatest challenges humankind faces worldwide. Increasing population growth, fast industrialization and modernization risk the worsening of water accessibility and quality in the coming years. Nanoadsorbents have steadily gained attention as remediation technologies that can meet stringent water quality demands. In this work, core-shell magnetic nanoparticles (MNPs) comprised of an iron oxide magnetic core and a styrene based polymer shell were synthesized via surface initiated atom transfer radical polymerization (SI-ATRP), and characterized them for their binding of polychlorinated biphenyls (PCBs), as model organic contaminants. Acrylated plant derived polyphenols, curcumin multiacrylate (CMA) and quercetin multiacrylate (QMA), and divinylbenzene (DVB) were incorporated into the polymeric shell to create high affinity binding sites for PCBs. The affinity of these novel materials for PCB 126 was evaluated and fitted to the nonlinear Langmuir model to determine binding affinities (K). The K values obtained for all the MNP systems showed higher binding affinities for PCB 126 that carbonaceous materials, like activated carbon and graphene oxide, the most widely used adsorption materials for water remediation today. The effect of increasing ATRP reaction time on the binding affinity of MNPs demonstrated the ability to tune polymer shell thickness by modifying the reaction extent and initial crosslinker concentrations in order to maximize pollutant binding. The enhancement in binding affinity and capacity for PCB 126 was demonstrated by the use of hydrophobic, aromatic rich molecules like styrene, CMA, QMA and DVB, within the polymeric shell provides more sites for π-π interactions to occur between the MNP surface and the PCB molecules. Overall, the high affinities for PCBs, as model organic pollutants, and magnetic capabilities of the core-shell MNPs synthesized provide a strong rationale for their application as nanoadsorbents in the environmental remediation of specific harmful contaminants.

Predicting degradation behavior of biodegradable metals is crucial for the clinical success of medical devices. This paper reports on the effect of long-term static stress on degradation of magnesium alloys and further changes in mechanical integrity. AZ31B (H24) and ZE41A (T5) alloys were tested to evaluate stress corrosion cracking (SCC) in a physiological solution for 30 days and 90 days (ASTM G39 testing standard). Scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX) and micro-computed tomography (micro-CT) were used to characterize surface morphology and micro-structure of degraded alloys. The results show the different mechanisms of stress corrosion cracking for AZ31B (transgranular stress corrosion cracking, TGSCC) and ZE41A (intergranular stress corrosion cracking, IGSCC). AZ31B was more susceptible to stress corrosion cracking under a long term static load than ZE41A. In conclusion, we observed that long-term static loading accelerated crack propagation, leading to the loss of mechanical integrity.

We report the enhanced mechanical properties of AZ31 magnesium alloys by plasma electrolytic oxidation (PEO) coating in NaOH, NaSiO, KF and NaHPO·2HO containing electrolytes. Mechanical properties including wear resistance, surface hardness and elastic modulus were increased for PEO-coated AZ31 Mg alloys (PEO-AZ31). DC polarization in Hank's solution indicating that the corrosion resistance significantly increased for PEO-coating in KF-contained electrolyte. Based on these results, the PEO coating method shows promising potential for use in biodegradable implant applications where tunable corrosion and mechanical properties are needed.

We report a straightforward route for preparing bulk quantities of size-controlled and low size dispersity copper oxide nanoclusters on amorphous silica. Adsorption of the copper-dendrimer complex on the silica surface minimizes aggregation, which results in previously unachieved low size dispersity of the nanoclusters. Copper oxide nanoclusters with mean diameters of 1-5 nm with size dispersities of only 8-15% were prepared by calcination of silica impregnated with Cu(II)-poly(propylene imine) dendrimer complexes of varying stoichiometry. The size and size distribution of the copper oxide nanoparticles are tunably controlled by the ratio of the Cu(II) to the terminal primary amines in the copper-dendrimer complex, DAB-Am -Cu(II) , the surface coverage of the DAB-Am -Cu(II) , and the impregnation procedure. This method is anticipated to be useful in the preparation of other metal oxide nanoparticles, e.g., Ni and Fe, and with other oxide substrates.