Thin-film nanocomposite (TFN) membranes are emerging water-purification membranes that could provide enhanced water permeance with similar solute removal over traditional thin-film composite (TFC) membranes. However, the effects of nanofiller incorporation on active layer physico-chemical properties have not been comprehensively studied. Accordingly, we aimed to understand the correlation between nanofillers, active layer physico-chemical properties, and membrane performance by investigating whether observed performance differences between TFN and control TFC membranes correlated with observed differences in physico-chemical properties. The effects of nanofiller loading, surface area, and size on membrane performance, along with active layer physico-chemical properties, were characterized in TFN membranes incorporated with Linde Type A (LTA) zeolite and zeolitic imidazole framework-8 (ZIF-8). Results show that nanofiller incorporation up to ~0.15 wt% resulted in higher water permeance and unchanged salt rejection, above which salt rejection decreased 0.9-25.6% and 26.1-48.3% for LTA-TFN and ZIF-8-TFN membranes, respectively. Observed changes in active layer physico-chemical properties were generally unsubstantial and did not explain observed changes in TFN membrane performance. Therefore, increased water permeance in TFN membranes could be due to preferential water transport through porous structures of nanofillers or along polymer-nanofiller interfaces. These findings offer new insights into the development of high-performance TFN membranes for water/ion separations.

The ongoing coronavirus pandemic (COVID-19) throughout the world has severely threatened the global economy and public health. Due to receiving severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) from a wide variety of sources (e.g., households, hospitals, slaughterhouses), urban sewage treatment systems are regarded as an important path for the transmission of waterborne viruses. This review presents a quantitative profile of the concentration distribution of typical viruses within wastewater collection systems and evaluates the influence of different characteristics of sewer systems on virus species and concentration. Then, the efficiencies and mechanisms of virus removal in the units of wastewater treatment plants (WWTPs) are summarized and compared, among which the inactivation efficiencies of typical viruses by typical disinfection approaches under varied operational conditions are elucidated. Subsequently, the occurrence and removal of viruses in treated effluent reuse and desalination, as well as that in sewage sludge treatment, are discussed. Potential dissemination of viruses is emphasized by occurrence via aerosolization from toilets, the collection system and WWTP aeration, which might have a vital role in the transmission and spread of viruses. Finally, the frequency and concentration of viruses in reclaimed water, the probability of infection are also reviewed for discussing the potential health risks.

Desalination drinking water systems and industrial processes generating high salinity streams require practical brine management options for disposal and/or treatment. Treatment most often involves large capacity brine concentrating processes, on the order of 2000 m/day, that rely on water evaporation, vapor compression, and condensation. A new technology adds an aerosol-generating device to the evaporation step with the goal of energy efficient operation even at smaller scales. The principles behind the tornadic flowfield that breaks up and aerosolizes water as air and water flow over the machined surface in the device are introduced. Design of a 6.8 m/day demonstration system, based on this new technology, producing a NaCl slurry (55 wt% solids) from a 22 wt% NaCl influent is described. Simulations of the system with three influent brine concentrations and three forms of final NaCl concentrate are presented and predicted energy usage is compared to estimates for conventional systems. By varying simulation process parameters, the heat transfer performance of the evaporator/condenser is identified as having a large impact on overall efficiency. The new system is anticipated to be most competitive, on an energy usage basis, with conventional concentrator/crystallizer systems when processing higher salinity brines and producing final concentrates containing precipitated NaCl.

The COVID-19 pandemic disturbed the world from the beginning of 2020. The high excessive number of patients and the presence of the SARS-CoV-2 in human excreta and urine even after the infected person's respiratory tests were negative, results in a heavy load of viral in various water bodies and mostly untreated wastewaters. In the present study, the reliability of using small-scale solar thermal desalination systems (solar stills) during a situation like the COVID-19 pandemic is discussed. Pollution of water bodies through the SARS-CoV-2 via numerous routes increases the risk of contaminating the feed water and subsequently the whole structure of solar stills. Since the transmission of pathogens (particle size: 0.5-3 μm) via droplets of water in solar still is reported before, transmitting of SARS-CoV-2 via droplets of water which multiple times smaller (particle size: 60-140 nm) than those pathogens is a concern. The most important issue which must be highlighted is that solar stills worked at low-temperature while the viability and survival of the SARS-CoV-2 in various water matrices in the temperature range (4-37 °C) for several days is reported. In this regard, using solar stills during the COVID-19 pandemic need further consideration by all researchers and people around the world.

Whilst the efficiency of reverse electrodialysis (RED) for thermal-to-electrical conversion has been theoretically demonstrated for low-grade waste heat, the specific configuration and salinity required to manage power generation has been less well described. This study demonstrates that operating RED by recycling feed solutions provides the most suitable configuration for energy recovery from a fixed solution volume, providing a minimum unitary cost for energy production. For a fixed membrane area, recycling feeds achieves energy efficiency seven times higher than single pass (conventional operation), and with an improved power density. However, ionic transport, water flux and concentration polarisation introduce complex temporal effects when concentrated brines are recirculated, that are not ordinarily encountered in single pass systems. Regeneration of the concentration gradient at around 80% energy dissipation was deemed most economically pragmatic, due to the increased resistance to mass transport beyond this threshold. However, this leads to significant exergy destruction that could be improved by interventions to better control ionic build up in the dilute feed. Further improvements to energy efficiency were fostered through optimising current density for each brine concentration independently. Whilst energy efficiency was greatest at lower brine concentrations, the work produced from a fixed volume of feed solution was greatest at higher saline concentrations. Since the thermal-to-electrical conversion proposed is governed by volumetric heat utilisation (distillation to reset the concentration gradient), higher brine concentrations are therefore recommended to improve total system efficiency. Importantly, this study provides new evidence for the configuration and boundary conditions required to realise RED as a practical solution for application to sources of low-grade waste heat in industry.

This paper examines the cost competitiveness of an extra-large-scale (275,000 m/d) solar-powered desalination, taking as a case study the Chtouka Ait Baha plant in Morocco. It assesses the conditions at which solar Photovoltaics (PV) and Concentrated Solar Power (CSP) would be competitive with a grid (mainly fossil) driven desalination plant for the reference year and by 2030. The paper considers also a scenario where battery storage complements PV power generation. To conduct the analysis, a simple model of water cost calculation is built. Second, the cost related to energy consumption is calculated for different power supply options to evaluate the impact of energy provision cost on the final cost of water. The first main result of this paper is that desalinated water can be obtained at an acceptable cost of around 1 $/m. The second one is that PV without storage remains the cheapest power supply option today and by 2030. Storage based solution appears less competitive today but can be more attractive in a framework of increasing electricity grid prices and higher flexibility requirements in the future. The paper gives recommendations regarding the implication of different technology choices in the framework of the future Moroccan energy system.

Global demand for water is rising. A sustainable and energy efficient approach is needed to desalinate brackish sources for agricultural and municipal water use. Genetic variation among two algae species, species ( sp.) and (), in their tolerance and uptake of salt (NaCl) was examined for potential bio-desalination of brackish water. Salt-tolerant hyper-accumulators were evaluated in a batch photobioreactors over salinity concentration ranging from 2 g/L to 20 g/L and different nutrient composition for their growth rate and salt-uptake. During algae growth phase, the doubling time varied between 0.63 and 1.81 days for sp. and 3.1 to 5.9 for . The initial salt-uptake followed pseudo first order kinetics where the rate constant ranged between -3.58 and -7.68 day reaching up to 30% in a single cycle. The halophyte algae sp. and that were selected for pilot-scale studies here represent a promising new method for desalination of brackish waters. Halophytic technologies combined with the potential use of algae for biofuel, which offsets energy demand, can provide a sustainable solution for clean, affordable water and energy.

Herein, we report on changes in the performance of a commercial cellulose triacetate (CTA) membrane, imparted by varied operating conditions and solution chemistries. Changes to feed and draw solution flow rate did not significantly alter the CTA membrane's water permeability, salt permeability, or membrane structural parameter when operated with the membrane skin layer facing the draw solution (PRO-mode). However, water and salt permeability increased with increasing feed or draw solution temperature, while the membrane structural parameter decreased with increasing draw solution, possibly due to changes in polymer intermolecular interactions. High ionic strength draw solutions may de-swell the CTA membrane via charge neutralization, which resulted in lower water permeability, higher salt permeability, and lower structural parameter. This observed trend was further exacerbated by the presence of divalent cations which tends to swell the polymer to a greater extent. Finally, the calculated CTA membrane's structural parameter was lower and less sensitive to external factors when operated in PRO-mode, but highly sensitive to the same factors when the skin layer faced the feed solution (FO-mode), presumably due to swelling/de-swelling of the saturated porous substructure by the draw solution. This is a first attempt aimed at systematically evaluating the changes in performance of the CTA membrane due to operating conditions and solution chemistry, shedding new insight into the possible advantages and disadvantages of this material in certain applications.

In China, the number of hospitals has increased to 19,712 in 2008, with the production of hospital wastewater reaching 1.29 × 10 m/d. Membrane bioreactor (MBR) technology presents a more efficient system at removing pathological microorganism compared with existing wastewater treatment systems. In the past 8 yr, over 50 MBR plants have been successfully built for hospital wastewater treatments, with the capacity ranging from 20 to 2000 m/d. MBR can effectively save disinfectant consumption (chlorine addition can decrease to 1.0 mg/L), shorten the reaction time (approximately 1.5 min, 2.5-5% of conventional wastewater treatment process), and attain a good effect of inactivation of microorganism. Higher disinfection efficacy is achieved in MBR effluents at lower dose of disinfectant with less disinfection by-products (DBPs). Moreover, when capacity of MBR plants increases from 20 to 1000 m/d, their operating cost decreases sharply.