The control of mercury in the air emissions from coal-fired power plants is an on-going challenge. The native unburned carbons in fly ash can capture varying amounts of Hg depending upon the temperature and composition of the flue gas at the air pollution control device, with Hg capture increasing with a decrease in temperature; the amount of carbon in the fly ash, with Hg capture increasing with an increase in carbon; and the form of the carbon and the consequent surface area of the carbon, with Hg capture increasing with an increase in surface area. The latter is influenced by the rank of the feed coal, with carbons derived from the combustion of low-rank coals having a greater surface area than carbons from bituminous- and anthracite-rank coals. The chemistry of the feed coal and the resulting composition of the flue gas enhances Hg capture by fly ash carbons. This is particularly evident in the correlation of feed coal Cl content to Hg oxidation to HgCl, enhancing Hg capture. Acid gases, including HCl and HSO and the combination of HCl and NO, in the flue gas can enhance the oxidation of Hg. In this presentation, we discuss the transport of Hg through the boiler and pollution control systems, the mechanisms of Hg oxidation, and the parameters controlling Hg capture by coal-derived fly ash carbons.

Large outdoor fires are an increasing danger to the built environment. Wildfires that spread into communities, labeled as Wildland-Urban Interface (WUI) fires, are an example of large outdoor fires. Other examples of large outdoor fires are urban fires including those that may occur after earthquakes as well as in informal settlements. When vegetation and structures burn in large outdoor fires, pieces of burning material, known as firebrands, are generated, become lofted, and may be carried by the wind. This results in showers of wind-driven firebrands that may land ahead of the fire front, igniting vegetation and structures, and spreading the fire very fast. Post-fire disaster studies indicate that firebrand showers are a significant factor in the fire spread of multiple large outdoor fires. The present paper provides a comprehensive literature summary on the role of firebrand mechanisms on large outdoor fire spread. Experiments, models, and simulations related to firebrand generation, lofting, burning, transport, deposition, and ignition of materials are reviewed. Japan, a country that has been greatly influenced by ignition induced by firebrands that have resulted in severe large outdoor fires, is also highlighted here as most of this knowledge remains not available in the English language literature. The paper closes with a summary of the key research needs on this globally important problem.